Download Ebook The Nature of the Hydrogen Bond Outline of a Comprehensive Hydrogen Bond Theory (International Union of Crystallography Monographs on Crystallography)
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Book Details :
Published on: 2009-06-25
Released on: 2009-06-25
Original language:
Hydrogen bond (H-bond) effects are known: it makes sea water liquid, joins cellulose microfibrils in trees, shapes DNA into genes and polypeptide chains into wool, hair, muscles or enzymes. Its true nature is less known and we may still wonder why O-H...O bond energies range from less than 1 to more than 30 kcal/mol without apparent reason. This H-bond puzzle is re-examined here from its very beginning and presented as an inclusive compilation of experimental H-bondenergies and geometries.New concepts emerge from this analysis: new classes of systematically strong H-bonds (CAHBs and RAHBs: charge- and resonance-assisted H-bonds); full H-bond classification in six classes (the six chemical leitmotifs); and assessment of the covalent nature of strong H-bonds. This leads to three distinct but inter-consistent models able to rationalize the H-bond and predict its strength, based on classical VB theory, matching of donor-acceptor acid-base parameters (PA or pKa), or shape of theH-bond proton-transfer pathway.Applications survey a number of systems where strong H-bonds play an important functional role, namely drug-receptor binding, enzymatic catalysis, ion-transport through cell membranes, crystal design and molecular mechanisms of functional materials. Brown_freq Compleat Lexical Tutor brown_freq worrisome worry worry-worryin worrying worse worsened worsens worship worshiped worshipful worshiping worshipped worshippers worshipping worst worst-marked Le Live Marseille : aller dans les plus grandes soires ... Retrouvez toutes les discothque Marseille et se retrouver dans les plus grandes soires en discothque Marseille. Loot.co.za: Sitemap 9781408682340 1408682346 Memorial Addresses On The Life And Character Of John G. Warwick A Representative From Ohio; Various 9780174900245 0174900244 Advanced GNVQ ... 35000 Ebooks Available for Download (Browse Titles 1 of 6 ... I have 34873 ebooks and audiobooks available for download in exchange for bitcoins. I will sell them for $1 each but I won't handle less than a $50 order. The more ... Full text of "NEW " - Internet Archive Search the history of over 279 billion web pages on the Internet. PHARMACEUTICAL MANUFACTURING HANDBOOK Production and Processes SHAYNE COX GAD PH.D. D.A.B.T. Gad Consulting Services Cary North Carolina CONTRIBUTORS ...
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